Porous materials are of scientific and techlogical importance because of the presence of voids of controllable dimensions at the atomic, molecular, and nameter scales, enabling them to discriminate and interact with molecules and clusters. Interestingly the big deal about this class of materials is about the thingness within - the pore space. International Union of Pure and Applied Chemistry (IUPAC) classifies porous materials into three categories - micropores of less than 2 nm in diameter, mesopores between 2 and 50 nm, and macropores of greater than 50 nm. In this book, naporous materials are defined as those porous materials with pore diameters less than 100 nm.Over the last decade, there has been an ever increasing interest and research effort in the synthesis, characterization, functionalization, molecular modeling and design of naporous materials. The main challenges in research include the fundamental understanding of structure-property relations and tailor-design of nastructures for specific properties and applications. Research efforts in this field have been driven by the rapid growing emerging applications such as biosensor, drug delivery, gas separation, energy storage and fuel cell techlogy, nacatalysis and photonics. These applications offer exciting new opportunities for scientists to develop new strategies and techniques for the synthesis and applications of these materials.This book provides a series of systematic reviews of the recent developments in naporous materials. It covers the following topics: (1) synthesis, processing, characterization and property evaluation; (2) functionalization by physical and/or chemical treatments; (3) experimental and computational studies on fundamental properties, such as catalytic effects, transport and adsorption, molecular sieving and biosorption; (4) applications, including photonic devices, catalysis, environmental pollution control, biological molecules separation and isolation, sensors, membranes, hydrogen and energy storage, etc.