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Metal Complex Catalysts Supercritical Fluid Polymerization Supramolecular Architecture (Paperback, 2013)

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Thepolymerizationofole nsanddi-ole nsisoneofthemostimportanttargets inpolymerscience.Thisreviewarticledescribesrecentprogressinthis eldand deals with organo-transition metal complexes as polymerization catalysts. - cent developments in organometallic chemistry have prompted us to nd a precise description of the mechanism of propagation, chain transfer, and terminationstepsinthehomogeneouslymetal-assistedpolymerizationofole ns anddiole ns.Thus,thisdevelopmentprovidesanideafordesigninganycatalyst systems that are of interest in industry. Recently,the agostic interactionofalkylgroup(s)ontransitionmetalshas emerged as highly basic and new concept and is found to be important in understandingthemechanismofthemetal-catalyzedhomogeneousoligomer- ation and polymerization of a-ole ns. Early transition metal alkyl complexes generallyhavepartiallyionicM-C bondsandshowa-agostichydrogeninter- tion that somewhat stabilizes the catalytically active species by providing el- tronsatavacantsite onthe metal.Thisisinsharp contrasttothefactthatlate transition metal alkyl complexes show mainly b-agostic hydrogen interaction that causes the hydrogen transfer easily through b-hydrogen elimination and reductive elimination, and that gives rise to the oligomerization of ole ns. Organometalliccomplexesoftheearlyandlatetransitionmetalshavebeenused as catalysts for ole n oligomerization and polymerization. The mechanism involved in these catalyst systems depends very much upon the kind of metal centersaswellastheirco-ligands,andthusthedi?erentmechanismswhichcan bedistinguishedbydetailedinvestigationsshouldbeassumedforearlyandlate transition metal catalysts. In this contribution, we review the mechanism of polymerization and oligomerization involving early transition metals, taking as our basis recent resultsinadvancedorganometallicchemistry.Firstofall,somerecentexamples of the previous reviews concerning the Ziegler-Natta polymerization are cited [1-10]. Then, relevant new reports are surveyed in a systematic fashion.

Product Identifiers

Publisher
Y. Nakayama, E. Ihara, H. Yasuda, A. Nakamura, J.M. Desimone, D.A. Canelas, A. Harada, K. Mashima, Springer-Verlag Berlin and Heidelberg Gmbh & Co. Kg
ISBN-13
9783662147931
eBay Product ID (ePID)
190509092

Product Key Features

Publication Name
Metal Complex Catalysts Supercritical Fluid Polymerization Supramolecular Architecture
Format
Paperback
Language
English
Subject
Chemistry, Physics
Publication Year
2013
Type
Textbook
Number of Pages
207 Pages

Dimensions

Item Height
235mm
Item Width
155mm
Volume
133
Item Weight
338g

Additional Product Features

Series Title
Advances in Polymer Science
Country/Region of Manufacture
Germany

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Metal Complex Catalysts Supercritical Fluid Polymerization Supramolecular Architecture (Paperback, 2013)

About this product

Product Information

Product Identifiers

Product Key Features

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Additional Product Features

Best Selling in Adult Learning & University

The Weed Forager's Handbook: A Guide to Edible and Medicinal Weeds in Australia by Adam Grubb, Annie Raser-Rowland (2012, Paperback)

Australian Native Bee Book: Keeping Stingless Bee Hives for Pets, Pollination and Sugarbag Honey by Tim Heard (Paperback, 2015)

The Falsification of History: Our Distorted Reality by John Hamer (Paperback, 2013)

Permaculture: A Designer's Manual by Bill Mollison (Hardcover, 1988)

In-Basket Case Studies by Guy Adamson (Paperback, 1986)

Empire of the Summer Moon: Quanah Parker and the Rise and Fall of the Comanches, the Most Powerful Indian Tribe in American History by S.C. Gwynne (Paperback, 2011)

Botanical Field Guide by Stefan Mager (Fold-out book or chart, 2021)

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