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Radical Reactions of Fullerenes and their Derivatives by O. Kalina, B.L. Tumanskii (Paperback, 2010)

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Product Information

The discovery of fullerenes has opened novel opportunities for radical chemistry. The fullerenyl radical adducts formed via addition of atoms or free radicals to fullerenes have no analogs in organic chemistry. Thus, the elucidation of the characteristic features of fullerenyl radicals and their reactivity by EPR spectroscopy is of fundamental importance. Isolation of the products from homolytic reactions of fullerenes in bulk amounts opens the door to large-scale preparation of new organic and organoelement derivatives of C60, including biologically active ones. Radical reactions of fullerenes find wide application in the synthesis of fullerene-containing polymers with valuable photophysical characteristics. Ferromagnetism of the complex of C60 with tetra(dimethylamino)ethylene lends impetus to a search for novel methods for preparation of biradicals, with one unpaired electron located on the fullerene cage and the other retained by the addend. This book covers the results of studies on homolytic reactions of fullerenes, the structures and reactivities of fullerenyl radicals performed by EPR, quantum-chemical, and other methods. Examples of the application of radical reactions of fullerenes in the synthesis and typical methods for their investigation are given. This book is intended for researchers working in chemistry of homolytic reactions as well as for fullerene scientists.

Product Identifiers

Publisher
Springer
ISBN-13
9789048158928
eBay Product ID (ePID)
178331195

Product Key Features

Author
O. Kalina, B.L. Tumanskii
Publication Name
Radical Reactions of Fullerenes and Their Derivatives
Format
Paperback
Language
English
Subject
Chemistry
Publication Year
2010
Type
Textbook
Number of Pages
193 Pages

Dimensions

Item Height
235mm
Item Width
155mm
Volume
2
Item Weight
332g

Additional Product Features

Title_Author
B.L. Tumanskii, O. Kalina
Series Title
Developments in Fullerene Science
Country/Region of Manufacture
Netherlands

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