Naporous Adic Alumina has received significant attention of the world researchers as a template for the low cost fabrication of nastructures of metals, semiconductors, polymers, superconductors, etc. In the present work it has been demonstrated that the type of electropolishing pre-treatment and the resulting na-features on aluminum surface can influence the hexagonal ordering of the pores developed during adizing. Apart from improving the ordering quality the work has been extended to relate the photoluminescence with the ordering quality of adic alumina, prepared at a given adizing voltage. New templates have been prepared, based on sandwiched structures. The two layers for the sandwiched structures were prepared by complete adization of aluminum sheet from opposite sides and by changing the adizing conditions, forming a new superlattice. Employing adic alumina as a template, elctrodeposition of nickel nawires in aqueous medium and in Dimethyl sulfoxide (DMSO) has been demosntrated. Silver nawires have also been grown in the template with electrochemical (AC) and electroless deposition techniques.