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Physical Chemistry : Thermodynamics, Statistical Mechanics, and Kinetics by Andrew Cooksy (2013, Hardcover)

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Key Benefit: Andrew Cooksy's clear teaching voice help students connect immediately with the subject matter while defusing some of their initial trepidation about physical chemistry. Through lively narrative and meticulous explanations of mathematical derivations, Physical Chemistry: Thermodynamics, Statistical Mechanics, and Kinetics engages students while fostering a sincere appreciation for the interrelationship between the theoretical and mathematical reasoning that underlies the study of physical chemistry. The author's engaging presentation style and careful explanations make even the most sophisticated concepts and mathematical details clear and comprehensible. Key Topics: Properties of the Microscopic World, Bulk properties, Entropy, The ideal gas and translational states, The ideal gas law, Separation of Degrees of Freedom, The equipartition principle, Vibrational and rotational partition functions, The Translational Density of States, The translational partition function, Temperature and the Maxwell-Boltzmann distribution, Extrapolation to many molecules, Pressure of a non-ideal fluid, Averaging the dipole-dipole potential, Bose-Einstein and Fermi-Dirac statistics, Statistics of molecular collisions, Transport without external forces, Transport with external forces, Conduction, convection, and radiation, Blackbody radiation, Spectroscopic intensities, Laser dynamics, Spectroscopic linewidths, Conclusion to Part IV: E, U, Ndof, S, The first law of thermodynamics, Approximations and assumptions, Mathematical tools, Computer simulations, Heat capacities, Expansion of gases, Entropy of an ideal gas, The second law of thermodynamics, The third law of thermodynamics, Ideal mixing, Phase transitions, Thermodynamics of phase transitions, Chemical potentials, Statistical mechanics of vaporization, Phase diagrams, The standard states, Statistical mechanics of solutions, Thermodynamics of solutions, Ionic solutions, Applications of the activity, Conclusion to Part V: E, U, Ndof, S, Introduction to chemical reactions, Enthalpies of reaction, Spontaneous chemical reactions, Chemical equilibrium, Reaction rates, Simple collision theory, Transition state theory, Diffusion-limited rate constants, Rate laws for elementary reactions, Elements of multi-step reactions, Approximations in kinetics, Chain reactions, Atmospheric chemistry, Combustion chemistry, Molecular astrophysics, Enzyme catalysis, Mathematics, Classical physics, Quantum mechanics and classical mechanics, Mathematical tools of quantum mechanics, Fundamental examples, Solving the one-electron atom Schr odinger equation, The one-electron atom orbital wave functions, Electric dipole interactions, Magnetic dipole interactions, Many-electron spatial wavefunctions, Computational methods, Spin wavefunctions and symmetrization, Vector model of the many-electron, Periodicity of the elements, The molecular Hamiltonian, The molecular wavefunction, Covalent bonds in polyatomic molecules, Non-covalent bonds, Nuclear magnetic resonance spectroscopy, Group theory, Symmetry representations for wavefunctions, Selection rules, Applications to asymmetric molecules, Application to H]uckel's rule, Molecular orbital configurations, Electronic states, Computational methods for molecules, Energetic processes, The vibrational Schr]odinger equation, Vibrational energy levels in diatomics, Vibrations in polyatomics, Spectroscopy of vibrational states, Rotations in Diatomics, Rotations in polyatomics, Spectroscopy of rotational states, Intermolecular potential energy, Molecular collisions, Clusters, Macromolecules, Nanometer-scale diagnostics and engineering, The qualitative nature of liquids, Pure liquids, Solvation, Amorphous solids, Crystals, Wavefunctions and energies of solids Market Intended for those who would like to gain a basic knowledge of physical chemistry.

Product Identifiers

Publisher
Pearson Education
ISBN-10
0321814150
ISBN-13
9780321814159
eBay Product ID (ePID)
159931921

Product Key Features

Author
Andrew Cooksy
Publication Name
Physical Chemistry : Thermodynamics, Statistical Mechanics, and Kinetics
Format
Hardcover
Language
English
Publication Year
2013
Type
Textbook
Number of Pages
576 Pages

Dimensions

Item Length
10in
Item Height
1in
Item Width
8in
Item Weight
44 Oz

Additional Product Features

Lc Classification Number
Qd453.3.C66 2014
Table of Content
Physical Chemistry at the Macroscopic Scale: Statistical Mechanics, Thermodynamics, and Kinetics A Introduction: Tools from Math and Physics A.1 Mathematics A.2 Classical Physics I Extrapolation to Macroscopic Systems 1 Introduction to Statistical Mechanics: Building Up to the Bulk 1.1 Properties of the Microscopic World 1.2 Bulk properties 1.3 Entropy 1.4 The ideal gas and translational states 1.5 The ideal gas law Problems 2 Partitioning the Energy 2.1 Separation of Degrees of Freedom 2.2 The equipartition principle 2.3 Vibrational and rotational partition functions 2.4 The Translational Density of States 2.5 The translational partition function 2.6 Temperature and the Maxwell-Boltzmann distribution Problems 3 Statistical Mechanics and Molecular Interactions 3.1 Extrapolation to many molecules 3.2 Pressure of a non-ideal fluid 3.3 Averaging the dipole-dipole potential 3.4 Bose-Einstein and Fermi-Dirac statistics 4 Mass Transport 4.1 Statistics of molecular collisions 4.2 Transport without external forces 4.3 Transport with external forces Problems 5 Energy transport 5.1 Conduction, convection, and radiation 5.2 Blackbody radiation 5.3 Spectroscopic intensities 5.4 Laser dynamics 5.5 Spectroscopic linewidths 5.6 Conclusion to Part IV: E, U, Ndof , S Problems II Non-Reactive Macroscopic Systems 6 Introduction to Thermodynamics 6.1 The first law of thermodynamics 6.2 Approximations and assumptions 6.3 Mathematical tools 6.4 Computer simulations Problems 7 Energy and Enthalpy 7.1 Heat capacities 7.2 Expansion of gases Problems 8 Entropy 8.1 Entropy of an ideal gas 8.2 The second law of thermodynamics 8.3 The third law of thermodynamics 8.4 Ideal mixing Problems 9 Phase Transitions and Phase Equilibrium 9.1 Phase transitions 9.2 Thermodynamics of phase transitions 9.3 Chemical potentials 9.4 Statistical mechanics of vaporization 9.5 Phase diagrams Problems 10 Solutions 10.1 The standard states 10.2 Statistical mechanics of solutions 10.3 Thermodynamics of solutions 10.4 Ionic solutions 10.5 Applications of the activity 10.6 Conclusion to Part V: E, U, Ndof , S Problems III Reactive Systems 11 Chemical Thermodynamics 11.1 Introduction to chemical reactions 11.2 Enthalpies of reaction 11.3 Spontaneous chemical reactions 11.4 Chemical equilibrium Problems 12 Elementary Reactions 12.1 Reaction rates 12.2 Simple collision theory 12.3 Transition state theory 12.4 Diffusion-limited rate constants 12.5 Rate laws for elementary reactions Problems 13 Multi-step Reactions 13.1 Elements of multi-step reactions 13.2 Approximations in kinetics 13.3 Chain reactions Problems 14 Reaction Networks 14.1 Atmospheric chemistry 14.2 Combustion chemistry 14.3 Molecular astrophysics 14.4 Enzyme catalysis 14.5 Conclusion to the text
Copyright Date
2014
Target Audience
College Audience
Topic
Mechanics / General, Chemistry / Physical & Theoretical, Chemistry / General, Mechanics / Thermodynamics
Lccn
2012-037313
Dewey Decimal
541
Dewey Edition
23
Illustrated
Yes
Genre
Science

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Physical Chemistry : Thermodynamics, Statistical Mechanics, and Kinetics by Andrew Cooksy (2013, Hardcover)

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