This is part of a general effort aimed at extending the range of molecular materials combining two properties in the same molecule and their tuning by changing the different electron ability of the metallocene and the radical units. The magnetic properties of different mono, bi and tri radicals have been studied.In addition, an interesting example of a photomagnetic system based on a supramolecular phenomenon in which a doublet species is converted into a singlet one is presented. Such ferrocene-polychlorotriphenylmethyl radicals present intramolecular electron transfer phenomenon which energy can be easily tuned by changing the substitutents of the donor or acceptor units or even the nature of the solvent. It is also described a novel valence tautomeric example combining an organic radical as acceptor unit and a ferrocene unit as the donor group. Finally, it has been proved that Ferrocene based polychlorotriphenylmethyl radicals systems also exhibits intense NLO responses that can be modulated at will simply tuning the donor and acceptor capabilities of the ferrocene and radical units.
Product Identifiers
Publisher
Lap Lambert Academic Publishing
ISBN-13
9783838313191
eBay Product ID (ePID)
104511038
Product Key Features
Author
Imma Ratera
Publication Name
A New Approach Towards Multiproperty Molecular Materials
Format
Paperback
Language
English
Subject
Chemistry
Publication Year
2010
Type
Textbook
Number of Pages
208 Pages
Dimensions
Item Height
229mm
Item Width
152mm
Item Weight
313g
Additional Product Features
Title_Author
Imma Ratera
Country/Region of Manufacture
Germany
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